Novel Hydrophobic Functionalized UiO-66 Series: Synthesis,Characterization, and Evaluation of Their Structural andPhysical–Chemical Properties

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dc.contributor.authorPilar Narea
dc.contributor.authorIván Brito
dc.contributor.authorYurieth Quintero
dc.contributor.authorEsteban Camú
dc.date.accessioned2026-04-10T14:58:40Z
dc.date.available2026-04-10T14:58:40Z
dc.date.issued2024
dc.description.abstractA novel set of four functionalized hydrophobic UiO-66-NHR series were synthesized through post synthetic procedures, utilizing various benzoyl chlorides and UiO-66-NH2as starting materials. This synthesis method was carried out by employing p- (1) and o-toluoyl (2), as well as2- (3)and 4-fluorobenzoyl (4) substituents. The analysis of the resulting compounds was performe dusing conventional spectroscopic methods such as FT-IR and1H NMR to quantify the conversion rate into amide. Furthermore, SEM and XPS techniques were employed for morphological and surface analysis. Finally, the evaluation of the chemical stability and contact angle using the sessile drop method was performed to evaluate the technological potential of these compounds for application ina queous and acidic media (such as selective separation of different metals and wastewater recovery
dc.description.sponsorshipAgencia Nacional de Investigación y Desarrollo (ANID-Chile) (Grant No. 21190030) Programa Beca Tesis Doctoral Mujer from “Fortalecimiento de la innovación y transferencia tecnológica en la Universidad de Antofagasta, code 99-INES of Oficina de Transferencia y Licenciamiento de la Universidad de Antofagasta Vicerrectoría de Investigación, Innovación y Postgrado (VRIIP-UA) and Dirección de Gestión de la Investigación(DGI_UA) for the “Ayudante de investigación 2023” contest of the Universidad de Antofagasta, Chile.
dc.identifier.doi10.3390/ijms25010199
dc.identifier.issn16616596
dc.identifier.urihttps://repositorioabierto.uantof.cl/handle/uantof/690
dc.language.isoen
dc.rightsAttribution 4.0 Internationalen
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.sourceInternational Journal of Molecular Sciences
dc.titleNovel Hydrophobic Functionalized UiO-66 Series: Synthesis,Characterization, and Evaluation of Their Structural andPhysical–Chemical Properties
dc.typeArticle
oaire.citation.volume85
organization.identifier.rorUniversidad de Antofagasta
uantof.identificator.departmentDepartamento de Química
uantof.identificator.facultyFacultad de Ciencias Básicas
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